We (and I mean Ryan because I alternated between standing on the bed yelling at him to catch it and standing in the bathtub yelling at him to kill it instead) caught the snake with the handle of a broom and a pair of tongs and dumped it into a mop bucket to be transported outside. Far from the house and me, where snakes belong.
In all fairness, it was just a baby Lampropeltis getula - Common Kingsnake. Its non-venomous and eats rodents and other snakes - which hopefully are not hanging out in my bathroom as well. The perks of having a Kingsnake really don't seem to matter all that much though when you are barefoot and in your pj's, just trying to do your business before bed.